UMN MRSEC | Publications

IRG-1: Ionic Control of Materials

IRG-1 Publications resulting from primary MRSEC support

Guo, S.; Yun, H.; Nair, S.; Jalan, B.; Mkhoyan, K.A. Mending cracks atom-by-atom in rutile TiO₂ with electron beam radiolysis. Nat. Commun. 2023, 14:6005.
DOI: 10.1038/s41467-023-41781-x
Primary data available here

Ghosh, S.; Liu, F.; Jalan, B.; Mkhoyan, K.A. Control of Extended Defect Growth in Perovskite Oxide Thin Films using Nanoscale Patterning. Microsc. Microanal., 2023, 29 (1), 541-542.
DOI: 10.1093/micmic/ozad067.255

Zhang, C.; Liu, F.; Guo, S.; Zhang, Y.; Xu, X.; Mkhoyan, K.A.; Jalan, B.; Wang, X. Temperature-dependent thermal conductivity of MBE-grown epitaxial SrSnO₃ films. Appl. Phys. Lett., 2023, 123 (4).
DOI: 10.1063/5.0156367
Primary data available here

Pramanik, S.; Trejo, N.; McIntire, E.; Hudson-Smith, N.V.; Tuga, B.; He, J.; Aydil, E.S.; Haynes, C.L. Transformations and Environmental Impacts of Copper Zinc Tin Sulfide Nanoparticles and Thin Films. ACS Applied Materials and Interfaces, 2023, 15 (20), 24978-24988.
DOI: 10.1021/acsami.3c00374

Chakraborty, R.D.; Postiglione, W.M.; Ghosh, S.; Mkhoyan, K.A.; Leighton, C.; Ferry, V.E. Optical properties of electrochemically gated La_1−xSr_xCoO_3−δ as a topotactic phase-change material. Adv. Opt. Mater. 2023, 11, 2300098.
DOI: 10.1002/adom.202300098
Primary data available here

Zhang, Y.; Postiglione, W.M.; Xie, R.; Zhang, C.; Zhou, H.; Chaturvedi, V.; Heltemes, K.; Zhou, H.; Feng, T.; Leighton, C.; Wang, X. Wide-range continuous tuning of the thermal conductivity of La_0.5Sr_0.5CoO_3-δ films via room-temperature ion-gel gating. Nat. Commun. 2023, 14, 2626,
DOI: 10.1038/s41467-023-38312-z
Primary data available here

Day-Roberts, E.; Fernandes, R.M.; Birol, T. Gating-induced Mott transition in NiS₂. Phys. Rev. B, 2023, 107, 085150,
DOI: 10.1103/PhysRevB.107.085150

Wang, H.; Postiglione, W.M.; Chaturvedi, V.; Runnerstrom, E.L.; Cleri, A.; Nordlander, J.; Maria, J.-P.; Leighton, C. Electrolyte-gate-driven carrier density modulation and metal–insulator transition in semiconducting epitaxial CdO films. APL Mater., 2022, 10, 121106.
DOI: 10.1063/5.0116294

Yun, H.; Gautreau, D.; Mkhoyan, K.A.; Birol, T. Strain effect on the ground-state structure of Sr₂ Sn0₄ Ruddlesden-Popper oxides. Phys. Rev. Mater., 2022, 6 (10), 104608.
DOI: 10.1103/PhysRevMaterials.6.104608
Primary data available here

Choudhary, R.; Nair, S.; Yang, Z.; Lee, D.; Jalan, B. Semi-metallic SrIrO₃ films using solid-source metal-organic molecular beam epitaxy. APL Mater., 2022, 10, 09118.
DOI: 10.1063/5.0110707
Primary data available here

Hameed, S.; Voigy, B.; Dewey, J.; Moore, W.; Pelc, D.; Das, B.; El-Khatib, S.; Garcia-Barriocanal, J.; Luo, B.; Seaton, N.; Yu, G.; Leighton, C.; Greven, M. Electrochemical mechanism of ionic-liquid gating in antiferromagnetic Mott-insulating NiS₂ single crystals. Phys. Rev. Mater., 2022,. 6, 064601.
DOI: 10.1103/PhysRevMaterials.6.064601

Yang, Z.; Lee, D.; Yue, J.; Jalan, B. Epitaxial SrTiO₃ films with dielectric constants exceeding 25,000. Proc. Nat. Acad. Sci., 2022, 119, 23.
DOI: 10.1073/pnas.2202189119

Leighton, C.L.; Birol, T.; Walter, J. What controls electrostatic vs. electrochemical response in electrolyte-gated materials? A perspective on critical materials factors. APL Mater., 2022, 10, 040901.
DOI: 10.1063/5.0087396

Bidoky, F.Z.; Frisbie, C.D. Sub-3V, MHz-Class Electrolyte-Gated Transistors and Inverters. ACS Appl. Mater. Interfaces, 2022, 14, 18, 21295-21300.
DOI: 10.1021/acsami.2c01585

He, T.; Frisbie, C.D. Sub-Band Filling, Mott-like Transitions, and Ion Size Effects in C₆₀ Single Crystal Electric Double Layer Transistors. ACS Nano, 2022,16, 4823-4830.
DOI: 10.1021/acsnano.2c00222

Zhang, Y.; Huang, D.; Zhang, C.; Wang, X. The spin-heat coupling and enabling applications. Journal of Applied Physics, 2022, 131 (4), 040902.
DOI: 10.1063/5.0073512

Zhang, Y.; Eslamisaray, M.A.; Feng, T.; Kortshagen, U.; Wang, X. Observation of suppressed diffuson and propagon thermal conductivity of hydrogenated amorphous silicon films.Nanoscale Adv., 2022, 4 (87).
DOI: 10.1039/d1na00557j

Rajapitamahuni, A.K.; Manjeshwar, A.K.; Kumar, A.; Datta, A.; Ranga, P.; Thoutam, L.R.; Krishnamoorthy, S.; Singisetti, U.; Jalan, B. Plasmon-Phonon Coupling in Electrostatically Gated β-Ga2O3 films with mobility exceeding 200 cm²V^-1s^-1. ACS Nano, 2022,16, 6, 8812-8819.
DOI: 10.1021/acsnano.1c09535

Thoutam, L.R; Truttmann, T.K.; Rajapitamahuni, A.K.; Jalan, B. Hysteretic Magnetoresistance in a Non-Magnetic SrSnO₃ Film via Thermal Coupling to Dynamic Substrate Behavior. Nano Lett., 2021, 21, 10006-10011.
DOI: 10.1021/acs.nanolett.1c03653

Chaturvedi, V.; Postiglione, W.M.; Chakraborty, R.D.; Yu, B.; Tabiś, W.; Hameed, S.; Biniskos, N.; Jacobson, A.; Zhang, Z.; Zhou, H.; Greven, M.; Ferry, V.E.; Leighton, C. Doping- and Strain-Dependent Electrolyte-Gate-Induced Perovskite to Brownmillerite Transformation in Epitaxial La_1–xSr_xCoO_3−δ Films. ACS Appl. Mater. Interfaces, 2021, 13 (43), 51205-51217.
DOI: 10.1021/acsami.1c13828
Primary data available here

He, T.; Stolte, M.; Wang, Y.; Renner, R.; Ruden, P.; Würthner, F.; Frisbie, C. D. Site-specific chemical doping reveals electron atmospheres at the surfaces of organic semiconductor crystals. Nat. Mater, 2021, 20, 1532-1538.
DOI: 10.1038/s41563-021-01079-z
Primary data available here

Ghosh, S.; Yun, H.; Kumar, P.; Conrad, S.; Tsapatsis, M.; Mkhoyan, K. A. ; Two Distinct Stages of Structural Modification of ZIF-L MOF under Electron-Beam Irradiation. Chem. Mater., 2021, 33, 5681-5689.
DOI: 10.1021/acs.chemmater.1c01332

Li, S.; Birol, T.; Free-Carrier-Induced Ferroelectricity in Layered Perovskites. Phys. Rev. Lett., 2021,127, 087601.
DOI: 10.1103/PhysRevLett.127.087601
Primary data available here

Yun, H.; Prakash, A.; Birol, T.; Jalan, B.; Mkhoyan, K.A. Dopant Segregation Inside and Outside Dislocation Cores in Perovskite BaSnO₃ and Reconstruction of the Local Atomic and Electronic Structures. Nano Lett., 2021, 21 (10), 4357–4364.
DOI: 10.1021/acs.nanolett.1c00966
Primary data available here

Rajapitamahuni, A.K.; Thoutam, L.R.; Ranga, P.; Krishnamoorthy, S.; Jalan, B. Impurity band conduction in Si-doped β-Ga₂O₃ films. Appl. Phys. Lett., 2021, 118, 072105.
DOI: 10.1063/5.0031481

Li, S.; Birol, T. Suppressing the ferroelectric switching barrier in hybrid improper ferroelectrics. npj Comput. Mater., 2020, 6 (168).
DOI: 10.1038/s41524-020-00436-x
Primary data available here

Wu, X.W.; Greenburg, B.L.; Zhang, Y.Y.; Held, J.T.; Huang, D.B.; Barriocanal, J.G.; Mkhoyan, K.A.; Aydil, E.S.; Kortshagen, U.; Wang, X. Thermal transport in ZnO nanocrystal networks synthesized by nonthermal plasma. Phys. Rev. Mater., 2020, 4, 086001.
DOI: 10.1103/PhysRevMaterials.4.086001

Huang, Y.; Shklovskii, B.I. Spectral rigidity of non-Hermitian symmetric random matrices near the Anderson transition. Phys. Rev. B, 2020, 102, 064212.
DOI: 10.1103/PhysRevB.102.064212
Primary data available here

IRG-1 Publications resulting from partial MRSEC support

Varshney, S.; Choo, S.; Thompson, L.; Yang, Z.; Shah, J.; Wen, J.; Koester, S.J.; Mkhoyan, K.A.; McLeod, A.S.; Jalan, B. Hybrid Molecular Beam Epitaxy for Single-Crystalline Oxide Membranes with Binary Oxide Sacrificial Layers. ACS Nano, 2024, 18, 8, 6348-6358.
DOI: 10.1021/acsnano.3c11192

Sharifi, S.; Shohan, R.; Hobosyan, M.A.; Lamichhane, U.; Chipara, M.; Mkhoyan, K.A.: Zakhidov, A.; Wang, Z.; Baughman, R.H.; Martirosyan, K.S. Carbon-based nanocomposite yarns reinforced with titanium carbide formed by internally reacted titanium and graphene. MRS Commun., 2024.
DOI: 10.1557/s43579-023-00512-5

Lu, B.; Stolte, M.; Liu, D.; Zhang, X.; Zhao, L.; Tian, L.; Frisbie, C.D.; Würthner, F.; Tao, X.; He, T. High Sensitivity and Ultra-Broad-Range NH₃ Sensor Arrays by Precise Control of Step Defects on The Surface of Cl₂-Ndi Single Crystals. Adv. Sci., 2024, 2308036.
DOI: 10.1002/advs.202308036

Shaffer, D.; Burnell, F.J.; Fernandes, R.F.Weak-coupling theory of pair density wave instabilities in transition metal dichalcogenides. Phys. Rev. B., 2023, 107, 224516.
DOI: 10.1103/PhysRevB.107.224516

Choudhary, R.; Liu, Z.; Cai, J.; Xu, X.; Chu, J.H.; Jalan, B. Growing clean crystals from dirty precursors: Solid-source metal-organic molecular beam epitaxy growth of superconducting Sr₂RuO₄ films. APL Mater., 2023, 11 (6), 061124.
DOI: 10.1063/5.0150893

Huang, D.; Zhang, D.; Kim, Y.; Wang, J.P.; Wang, X. Magnetization dynamics in synthetic antiferromagnets with perpendicular magnetic anisotropy. Phys. Rev. B, 2023, 107 (21), 214438.
DOI: 10.1103/PhysRevB.107.214438

Manjeshwar, A.K.; Nair, S.; Rajapitamahuni, A.K.; James, R.d.; Jalan, B. Adsorption-Controlled Growth and Magnetism in Epitaxial SrRuO₃ Films. ACS Nano, 2023.
DOI: 10.1021/acsnano.3c03625

Du, D.; Thoutam, L.R.; Genser, K.T.; Zhang, C.; Rabe, K.M.; Samanta, T.; Jung, T.; Jalan, B.; Voyles, P.M.; Kawasaki, J.K. Effect of Pt vacancies on magnetotransport of Weyl semimetal candidate GdPtSb epitaxial films. Phys. Rev. Mater., 2023, 7 (8), 084204.
DOI: 10.1103/PhysRevMaterials.7.084204

Nair, S.; Yang, Z.; Lee, D.; Guo, S.; Sadowski, J.T.; Johnson, S.; Saboor, A.; Li, Y.; Zhou, H.; Comes, R.B.; Jin, W.; Mkhoyan, K.A.; Janotti, A.; Jalan, B. Engineering metal oxidation using epitaxial strain. Nat. Nanotechnol., 2023.
DOI: 10.1038/s41565-023-01397-0
Primary data available here

Cho, K.G.; Adrahtas, D.Z.; Lee, K.H.; Frisbie, C.D. Sub-Band Filling and Hole Transport in Polythiophene-Based Electrolyte-Gated Transistors: Effect of Side-Chain Length and Density. Adv. Funct. Mater., 2023, 33 (37), 2303700.
DOI: 10.1002/adfm.202303700

Jindal, A.; Saha, A.; Li, Z.; Taniguchi, T.; Watanabe, K.; Hone, J.C.; Birol, T.; Fernandes, R.M.; Dean, C.R.; Pasupathy, A.N.; Rhodes, D.A. Coupled ferroelectricity and superconductivity in bilayer T_d-MoTe₂. Nature, 2023 613, 48-52.
DOI: s41586-022-05521-3

Dewey, J.E.; Ghosh, S.; Chaturvedi, V.; Postiglione, W.M.; Figari, L.; Jacobson, A.; Korostynski, C.; Charlton, T.R.; Mkhoyan, K.A.; Leighton, C. Anomalous strain relaxation and its impact on the valence-driven spin-state/metal-insulator transition in epitaxial (Pr_1-y Y_y ) _1-x Ca_x Co O _3-δ. Phys. Rev. Mater., 2023. 7, 024415.
DOI: 10.1103/PhysRevMaterials.7.024415

Chaturvedi, V.; Ghosh, S.; Gautreau, D.; Postiglione, W.M.; Dewey, J.E.; Quarterman, P.; Balakrishnan, P.P.; Kirby, B.J.; Zhou, H.; Cheng, H.; Huon, A.; Charlton, T.; Fitzsimmons, M.R.; Korostynski, C.; Jacobson, A.; Figari, L.; Garcia Barriocanal, J.; Birol, T.; Mkhoyan, K.A.; Leighton, C. Room-temperature valence transition in a strain-tuned perovskite oxide. Nat. Commun., 2022.
DOI: 10.1038/s41467-022-35024-8
Primary data available here

Lefler, B.M.; Postiglione, W.M.; Leighton, C.; May, S.J. Voltage Control of Patterned Metal/Insulator Properties in Oxide/Oxyfluoride Lateral Perovskite Heterostructures via Ion Gel Gating. Adv. Funct. Mater., 2022.
DOI: 10.1002/adfm.202208434

Fan, Y.; Cresswell, Z.; Guo, S.; Zhang, D.; Peterson, T.J.; Liu, J.; Lv, Y.; Mkhoyan, K.A.; Wang, J.-P. Observation of unidirectional spin Hall magnetoresistance in amorphous PtSn₄/CoFeB bilayers. Appl. Phys. Lett., 2022, 121, 092401.
DOI: 10.1063/5.0097355

Adiga, P.; Nunn, W.; Wong, C.; Manjeshwar, A.K.; Nair, S.; Jalan, B.; Stoerzinger, K.A. Breaking OER and CER scaling relations via strain and its relaxation in RuO₂ (101). Mater. Today Energy, 2022. 101087.
DOI: 10.1016/j.mtener.2022.101087
Primary data available here

Lyu, D.; Khanal, P.; Lv, Y.; Zhou, B.; Yun, H.; Jia, Q.; Zink, B.R.; Fan, Y.; Mkhoyan, K.A.; Wang, W.; Wang, J.-P. Sub-ns Switching and Cryogenic-Temperature Performance of Mo-Based Perpendicular Magnetic Tunnel Junctions. IEEE Elect. Dev. Lett., 2022, 43, 8, 1215-1218.
DOI: 10.1109/LED.2022.3184278

Kim, J.; Yun, H.; Seo, J.; Kim, J.H.; Kim, J.H.; Mkhoyan, K.A.; Kim, B.; Char, K. Deep-UV Transparent Conducting Oxide La-Doped SrSn0₃ with a High Figure of Merit. ACS Appl. Electron. Mater., 2022, 4, 7, 3623-3631.
DOI: 10.1021/acsaelm.2c00581

Zhang, P.; Chou, C-T.; Yun, H.; McGoldrick, B.C.; Hou, J.T.; Mkhoyan, K.A.; Liu, L. Control of Néel Vector with Spin-Orbit Torques in an Antiferromagnetic Insulator with Tilted Easy Plane. Phys. Rev. Lett., 2022, 129, 017203.
DOI: 10.1103/PhysRevLett.129.017203

Tanwar, M.; Udyavara, S.; Yun, H.; Ghosh, S.; Mkhoyan, A.; Neurock, M. Co-Operative Influence of O₂ and H₂O in the Degradation of Layered Black Arsenic. J. Phys., Chem. C, 2022, 126, 36, 15222-15228.
DOI: 10.1021/acs.jpcc.2c04861

Orth, P.P.; Phelan, D.; Zhao, J.; Zheng, H.; Mitchell, J.F.; Leighton, C.; Fernandes, R. Essential role of magnetic frustration in the phase diagrams of doped cobaltites. Phys. Rev. Mater., 2022, 6, L071402.
DOI: 10.1103/PhysRevMaterials.6.L071402

Onn, T.M.; Gathmann, S.R.; Wang, Y.; Patel, R.; Guo, S.; Chen, H.; Soeherman, J.K.; Christopher, P.; Rojas, G.; Mkhoyan, K.A.; Neurock, M.; Abdelrahman, O.A.; Frisbie, C.D.; Dauenhauer, P.J. Alumina Graphene Catalytic Condenser for Programmable Solid Acids. JACS Au, 2022, 2, 5.
DOI: 10.1021/jacsau.2c00114

Kim, D.; Ghosh, S.; Akter, N.; Kraetz, A.; Duan, X.; Kwak, K.; Rangnekar, N.; Johnson, J.R.; Narasimharao, K.; Malik, M.A.; Al-Thabaiti, S..; McCool, B.; Boscoboinik, J.A.; Mkhoyan, K.A.; Tsapatsis, M.. Twin-free, directly synthesized MFI nanosheets with improved thickness uniformity and their use in membrane fabrication. Sci. Adv., 2022, 8 (14).
DOI: 10.1126/sciadv.abm8162

Kundu, S.; Golani, P.; Yun, H.; Guo, S.; Youssef, K.M.; Koester, S.J.; Mkhoyan, K.A. Tunable metal contacts at layered black-arsenic/metal interface forming during metal deposition for device fabrication. Commun. Mater., 2022, 3 (1).
DOI: 10.1038/s43246-022-00233-7

El-Khatib, S.; Voigt, B.; Das, B.; Stahl, A.; Moore, W.; Maiti, M.; Leighton, C. Conduction via surface states in antiferromagnetic Mott-insulating Ni S₂ single crystals. Phys. Rev. Mater., 2021. 5, (11).
DOI: 10.1103/physrevmaterials.5.115003

Truttmann, T.K.; Zhou, J.J.; Lu, I.T.; Rajapitamahuni, A.K.; Liu, F.; Mates, T.E.; Bernardi, M.; Jalan, B. Combined experimental-theoretical study of electron mobility-limiting mechanisms in SrSnO₃. Comm. Phys., 2021, 4 (1).
DOI: 10.1038/s42005-021-00742-w

Zhao, W.; Veerappan, V.B.; Ghosh, S.; Li, X.; Geuzebroek, F.; El Nasr, A.S.; Khan, I.; Dara, S.; Mittal, N.; Daoutidis, P.; Al Hashimi, S.; Mkhoyan, K.A.; Al Wahedi, Y.; Tsapatsis, M.; Stein, A. High-Capacity Regenerable H₂S Sorbent for Reducing Sulfur Emissions. Ind. Eng. Chem. Res., 2021, 60 (41).
DOI: 10.1021/acs.iecr.1c02715

Majkic, G.; Jeong J.S.; Yun, H.; Robles, Hernandez F.C.; Galstyan, E.; Pratap, R.; Cheng, H.; Stokes, A.; Mkhoyan, K.A.; Selvamanickam, V. New insight into strain and composition of BaZrO₃ nanorods in REBCO superconductor. Supercond Sci Technol., 2021, 34.
DOI: 10.1088/1361-6668/ac23ba

Nunn, W.; Truttmann, T.K.; Jalan, B. A review of molecular-beam epitaxy of wide bandgap complex oxide semiconductors. J. Mater. Res., 2021.
DOI: 10.1557/s43578-021-00377-1

Nunn, W.; Nair, S.; Yun, H.; Kamath Manjeshwar, A.; Rajapitamahuni, A.K.; Lee, D.; Mkhoyan, K.A.; Jalan, B. Solid-source metal-organic molecular beam epitaxy of epitaxial RuO₂. APL Mater., 2021, 9 (9), 091112.
DOI: 10.1063/5.0062726

Dentelski, D.; Day-Roberts, E.; Birol, T.; Fernandes, R.M.; Ruhman, J. Robust gapless superconductivity in 4Hb−TaS₂. Phys. Rev. B, 2021, 103, 224522.
DOI: 10.1103/PhysRevB.103.224522

Trevino De Leo, C.; Dannangoda, G.C.; Hobosyan, M.A.; Held, J.T.; Safi Samghabadi, F.; Khodadadi, M.; Litvinov, D.; Mkhoyan, K.A.; Martirosyan, K.S. Carbon combustion synthesis of Janus-like particles of magnetoelectric cobalt ferrite and barium titanate. Ceram. Int., 2021, 47 (4), 5415-5422.
DOI: 10.1016/j.ceramint.2020.10.123

Dai, C.; Agarwal, K.; Bechtel, H.A.; Liu, C.; Joung, D.; Nemilentsau, A.; Su, Q.; Low, T.; Koester, S.J.; Cho, J-H. Hybridized Radial and Edge Coupled 3D Plasmon Modes in Self-Assembled Graphene Nanocylinders. Small, 2021, 17 (14).
DOI: 10.1002/smll.202100079

Neal, S.N.; Li, S.; Birol, T.; Musfeldt, J.L. Chemical bonding and Born charge in 1T-HfS₂. npj 2D Mater Appl, 2021, 5 (45).
DOI: 10.1038/s41699-021-00226-z
Primary data available here

Postiglione, W.M.; Ganguly, K.; Yun, H.; Jeong, J.S.; Jacobson, A.; Borgeson, L.; Jalan, B.; Mkhoyan, K.A.; Leighton, C. Structure-property relationships and mobility optimization in sputtered La-doped BaSnO₃ films: Toward 100cm²V⁻¹s⁻¹ mobility. Phys. Rev. Mater., 2021, 5, 044604.
DOI: 10.1103/PhysRevMaterials.5.044604

Saran Kumar Chaganti, V.R.; Golani, P.; Truttmann, T.K.; Liu,F.; Jalan, B.; Koester, S.J. Optimizing Ohmic contacts to Nd-doped n-type SrSnO₃. Appl. Phys. Lett, 2021, 118, 142104.
DOI: 10.1063/5.0027470

Voigt, B.; Das, B.; Carr, D.M.; Ray, D.; Maiti, M.;Moore, W.; Manno, M.; Walter, J.; Aydil, E.S.; Leighton, C. Mitigation of the internal p-n junction in CoS₂-contacted FeS₂ single crystals: Accessing bulk semiconducting transport. Phys. Rev. Mater., 2021, 5, 025405.
DOI: 10.1103/PhysRevMaterials.5.025405

Huang, D.; Lattery, D.; Wang, X.J. Materials Engineering Enabled by Time-Resolved Magneto-Optical Kerr Effect for Spintronic Applications. ACS Appl. Electron. Mater., 2021, 3 (1), 119–127.
DOI: 10.1021/acsaelm.0c00961

Yun, H.; Topsakal, M.; Prakash, A.; Jalan, B.; Jeong, J.S.; Birol, T.; Mkhoyan, K.A. Metallic line defect in wide-bandgap transparent perovskite BaSnO₃. Sci. Adv., 2021, 7 (3), eabd4449.
DOI: 10.1126/sciadv.abd4449
Primary data available here

Wen, J.; Saran Kumar Chaganti, V.R.; Truttmann, T.K.; Liu, F.; Jalan, B.; Koester, S.J. SrSnO₃ Metal-Semiconductor Field-Effect Transistor With GHz Operation. IEEE Electron Device Letters, 2021, 42 (1).
DOI: 10.1109/LED.2020.3040417

Fu, X.; Huang, Y.; Shi, Q.; Shklovskii, B.I.; Zudov, M.A.; Gardner, G.C.; Manfra, M.J. Hidden Quantum Hall Stripes in Al_xGa_1−xAs/Al_0.24Ga_0.76As Quantum Wells. Phys. Rev. Lett., 2020, 125, 236803.
DOI: 10.1103/PhysRevLett.125.236803

Saran Kumar Chaganti, V.R.; Truttmann, T.K.; Liu, F.; Jalan, B.; Koester, S.J. SrSnO₃ Field-Effect Transistors With Recessed Gate Electrodes. in IEEE Electron Device Letters, 2020, 41 (9), 1428-1431.
DOI: 10.1109/LED.2020.3011058

Prakash, A.; Wang, T.; Bucsek, A.; Truttmann, T.K.; Fali, A.; Cotrufo, M.; Yun, H.; Kim, J-W.; Ryan, P.J.; Mkhoyan, K.A.; Alù, A.; Abate, Y.; James, R.D.; Jalan, B. Self-Assembled Periodic Nanostructures Using Martensitic Phase Transformations. Nano Lett., 2020, 21 (3), 1246-1252.
DOI: 10.1021/acs.nanolett.0c03708

Yoo, Y.; Jeong, J.S.; Ma, R.; Koester, S.J.; Johns, J.E. Ultrathin One-Dimensional Molybdenum Telluride Quantum Wires Synthesized by Chemical Vapor Deposition. Chem. Mater., 2020, 32 (22), 9650–9655.
DOI: 10.1021/acs.chemmater.0c03264

IRG-2: Mesoscale Network Materials

IRG-2 Publications resulting from primary MRSEC support

Perales Rodriguez, C.; Mahanthappa, M.K.; Lodge, T.P. Lyotropic Phase Behavior of Coil-Bottlebrush Diblock Copolymers in Alkylimidazolium-Based Ionic Liquids. Macromolecules, 2024, xxxx, xxx-xxx.
DOI: 10.1021/acs.macromol.3c02451

Magruder, B.R.; Morse, D.C.; Ellison, C.J.; Dorfman, K.D. Boundary Frustration in Double-Gyroid Thin Films. ACS Macro Lett., 2024, 13, 382-388.
DOI: 10.1021/acsmacrolett.4c00026
Primary data available here

Cui, S.; Murphy, E.A.; Zhang, W.; Zografos, A.; Shen, L.; Bates, F.S.; Lodge, T.P. Cylinders-in-Undulating-Lamellae Morphology from ABC Bottlebrush Block Terpolymers. J. Am. Chem. Soc., 2024,146, 10, 6796–6805.
DOI: 10.1021/jacs.3c13543

Das, S.; Zheng, C.; Lodge, T.P.; Siepmann, J.I.; Mahanthappa, M.K.; Calabrese, M.A; Reineke, T.M. Self-Assembly of Unusually Stable Thermotropic Network Phases by Cellobiose-Based Guerbet Glycolipids. Biomacromolecules, 2024, 25, 2, 1291-1302.
DOI: 10.1021/acs.biomac.3c01266

Yang, S.-M.; Oh, J.; Magruder, B.R.; Kim, H.J.; Dorfman, K.D.; Mahanthappa, M.; Ellison, C.J. Surface Relief Terraces in Double Gyroid-Forming Polystyrene-block-Polylactide Thin Films. Phys. Rev. Mater., 2023, 7, 125601.
DOI: 10.1103/PhysRevMaterials.7.125601
Primary data available here

Chen, P.; Dorfman, K.D. Gaming self-consistent field theory: Generative block polymerphase discovery. Proc. Nat. Acad. Sci., 2023, 120, 45, e2308698120.
DOI: 10.1073/pnas.2308698120
Primary data available here

Park, S.J.; Bates, F.S.; Dorfman, K.D. Single Gyroid in H-shaped Block Copolymers. Phys. Rev. Mater., 2023, 7, 2054804.
DOI: 10.1103/PhysRevMaterials.7.105601
Primary data available here

Chen, P.; Bates, F.S.; Dorfman, K.D. Alternating Gyroid Stabilized by Surfactant-like Triblock Terpolymers in IS/SO/ISO Ternary Blends. Macromolecules, 2023, 56, 2568-2577.
DOI: 10.1021/acs.macromol.2c02485
Primary data available here

Park, S.J.; Bates, F.S.; Dorfman, K.D. Complex Phase Behavior in Binary Blends of AB Diblock Copolymer and ABC Triblock Terpolymer. Macromolecules, 2023, 56, 1278-1288.
DOI: 10.1021/acs.macromol.2c02216
Primary data available here

Cui, S.; Zhang, B.; Shen, L.; Bates, F.S.; Lodge, T.P. Core–Shell Gyroid in ABC Bottlebrush Block Terpolymers. J. Am. Chem. Soc., 2022, 144, 47, 21719-21727.
DOI: 10.1021/jacs.2c09674

Bose, S.; Padilla, V.; Salinas, A.; Ahmad, F.; Lodge, T.P.; Ellison, C.J.; Lozano, K., Hierarchical Design Strategies to Produce Internally Structured Nanofibers. Polym. Rev., 2022, 63, 3, 679-714.
DOI: 10.1080/15583724.2022.2132509

Chen, P.; Mahanthappa, M.K.; Dorfman, K.D. Stability of cubic single network phases in diblock copolymer melts. J Polym. Sci., 2022, 60, 2543-2552.
DOI: 10.1002/pol.20220318
Primary data available here

Liberman, L.; Coughlin, M.L.; Weigand, S.; Edmund, J; Bates, F.S.; Lodge, T.P. Impact of Side-Chain Length on the Self-Assembly of Linear-Bottlebrush Diblock Copolymers. Macromolecules, 2022. 55, 12.
DOI: 10.1021/acs.macromol.2c00758

Shen, Z.; Luo, K.; Park, S.J.; Li, D.; Mahanthappa, M.K.; Bates, F.S.; Dorfman, K.D.; Lodge, T.P.; Siepmann, J.I. Stabilizing a Double Gyroid Network Phase with 2 nm Feature Size by Blending of Lamellar and Cylindrical Forming Block Oligomers. JACS Au, 2022. 2, 6.
DOI: 10.1021/jacsau.2c00101

Cote, B.M.; Lenart, W.R.; Ellison, C.J.; Ferry, V.E. Surface Structure Dependent Circular Dichroism in Single and Double Gyroid Metamaterials. Adv. Optical Mater., 2022, 2200363.
DOI: 10.1002/adom.202200363
Primary data available here

Liberman, L.; Coughlin, M.; Weigand, S.; Bates, F.S.; Lodge, T.P. Phase Behavior of Linear-Bottlebrush Block Polymers. Macromolecules, 2022, 55, 7, 2821-2831.
DOI: 10.1021/acs.macromol.2c00337

Park, S-J.; Bates, F.S.; Dorfman, K.D. Alternating Gyroid in Block Polymer Blends. ACS Macro Lett., 2022, 11, 643-650.
DOI: 10.1021/acsmacrolett.2c00115
Primary data available here

Santa Chalarca, C.F.; Dalal, R.J.; Chapa, A.*; Hanson, M.G.; Reineke, T.M. Cation Bulk and pK_a Modulate Diblock Polymer Micelle Binding to pDNA. ACS Macro Lett., 2022, 11, 4, 588-594.
DOI: 1010.21/acsmacrolett.2c00015

Sethuraman, V.; Zheng, D.; Morse, D.C.; Dorfman, K.D. Adsorption of Charge Sequence-Specific Polydisperse Polyelectrolytes. Macromolecules, 2022, 55, 8, 3030-3038.
DOI: 10.1021/acs.macromol.1c02623
Primary data available here

Coughlin, M.L.; Edmund, J.; Bates, F.S.; Lodge, T.P. Temperature Dependence of Chain Conformations and Fibril Formation in Solutions of Poly(N-isopropylacrylamide)-Grafted Methylcellulose. Macromolecules, 2021, 55, 2, 550-558.
DOI: 10.1021/acs.macromol.1c02206

Park, S.J.; Cheong, G.K.; Bates, F.S.; Dorfman, K.D. Stability of the Double Gyroid Phase in Bottlebrush Diblock Copolymer Melts. Macromolecules, 2021,54, (19), 9063-9070.
DOI: 10.1021/acs.macromol.1c01654
Primary data available here

Shen, Z.; Sun, Y.; Lodge, T.P.; Siepmann, J.I. Development of a PointNet for Detecting Morphologies of Self-Assembled Block Oligomers in Atomistic Simulations. J. Phys. Chem. B, 2021, 125 (20).
DOI: 10.1021/acs.jpcb.1c02389
Primary data available here

Liberman, L.; Schmidt, P.W.; Coughlin, M.L.; Ya’akobi, A.M.; Davidovich, I.; Edmund, J.; Ertem, S.P.; Morozova, S.; Talmon, Y.; Bates, F.S.; Lodge, T.P. Salt-Dependent Structure in Methylcellulose Fibrillar Gels. Macromolecules, 2021, 54 (5), 2090-2100.
DOI: 10.1021/acs.macromol.0c02429
Primary data available here

Shen, Z.; Chen, Q.P.; Xie, S.; Lodge, T.P.; Siepmann, J.I. Effects of Electrolytes on Thermodynamics and Structure of Oligo(ethylene oxide)/Salt Solutions and Liquid–Liquid Equilibria of a Squalane/Tetraethylene Glycol Dimethyl Ether Blend. Macromolecules, 2021, 54 (3), 1120–1136.
DOI: 10.1021/acs.macromol.0c02270
Primary data available here

Coughlin, M.L.; Liberman, L.; Ertem, S.P.; Edmund, J.; Bates, F.S.; Lodge, T.P. Methyl cellulose solutions and gels: fibril formation and gelation properties. Progress in Polymer Science, 2021, 112, 101324.
DOI: 10.1016/j.progpolymsci.2020.101324

Metaxas, A.E.; Panwar, V.; Olson, R.L.*; Dutcher, C.S. Ionic strength and polyelectrolyte molecular weight effects on floc formation and growth in Taylor–Couette flows. Soft Matter, 2021, 17, 1246-1257.
DOI: 10.1039/D0SM01517B

Metaxas, A.E.; Coughlin, M.L.; Hansen, C.K.; Bates, F.S.; Lodge, T.P.; Dutcher, C.S. Microfluidic filament thinning of aqueous, fibrillar methylcellulose solutions. Phys. Rev. Fluids, 2020, 5 (11), 113302.
DOI: 10.1103/PhysRevFluids.5.113302

Sethuraman, V.; Dorfman, K. Origins of the suppression of fibril formation in grafted methylcellulose solutions. Phys. Rev. Mater., 2020, 4, 085601.
DOI: 10.1103/PhysRevMaterials.4.085601
Primary data available here

IRG-2 Publications resulting from partial MRSEC support

Linn, J.D.; Rodriguez, F.A.*; Calabrese, M.A. Cosolvent incorporation modulates the thermal and structural response of PNIPAM/silyl methacrylate copolymers. Soft Matter, 2024, xx, xxx-xxx.
DOI: 10.1039/D4SM00246F

Magruder, B.R.; Dorfman, K.D. Theory of Block Polymer Self-Assembly. ACS In Focus, 2024, 3.
DOI: 10.1021/acsinfocus.7e8001

Ahmed, S.; Keniry, M.; Anaya-Barbosa, N.; Padilla, V.; Javed, MD. N.; Gilkerson, R.; Narula, A.S.; Ibrahim, E.; Lozano, K. Oxymatrine Loaded Cross-Linked PVA Nanofibrous Scaffold: Design and Characterization and Anticancer Properties. Macromol. Biosci., 2023, 23, 2300098.
DOI: 10.1002/mabi.202300098

Ahmed, S.; Keniry, M.; Padilla, V.; Anaya-Barbosa, N.; Javed, MD. N.; Gilkerson, R.; Gomez, K.; Ashraf, A.; Narula, A.S.; Lozano, K. Development of pullulan/chitosan/salvianolic acid ternary fibrous membranes and their potential for chemotherapeutic applications. Int. J. Biol. Macromol. 2023, 250, 126187.
DOI: 10.1016/j.ijbiomac.2023.126187

Panwar, V.; Vargas, C.N.*; Dutcher, C.S. Dispersion and mixing dynamics of complex oil-in-water emulsions in Taylor–Couette flows. Phil. Trans. R. Soc. A, 2023, 381, 20220128.
DOI: 10.1098/rsta.2022.0128
Primary data available here

Lembke, H.K.; Espinasse, A.; Hanson, M.G.; Grimme, C.J.; Tan, Z.; Reineke, T.M.; Carlson, E.E. Cationic Polymers Enable Internalization of Negatively Charged Chemical Probes into Bacteria. ACS Chemical Biology, 2023, 18 (9), 2063-2072.
DOI: 10.1021/acschembio.3c00351

McCauley, P.J.; Huang, C.*; Porcar, L.; Kumar, S.; Calabrese, M.A. Evolution of flow reversal and flow heterogeneities in high elasticity wormlike micelles (WLMs) with a yield stress J. Rheology, 2023, 67, 661.
DOI: 10.1122/8.0000535

Neal, C.A.P.; Kresge, G.V.; Quan, M.C.; León, V*.; Chibambo, N.O.; Calabrese, M.A. Effect of nanoparticle loading and magnetic field application on the thermodynamic, optical, and rheological behavior of thermoresponsive polymer solutions. J. Vinyl Addit. Technol., 2022, 29, 795-812.
DOI: 10.1002/vnl.21968

Hanson, M.G.; Grimme, C.J.; Santa Chalarca, C.F.; Reineke, T.M. Cationic Micelles Outperform Linear Polymers for Delivery of Antisense Oligonucleotides in Serum: An Exploration of Polymer Architecture, Cationic Moieties, and Cell Addition Order. Bioconjugate Chemistry, 2022, 33 (11), 2121-2131.
DOI: 10.1021/acs.bioconjchem.2c00379

Neal, C.A.P.; León, V.*; Quan, M.C.; Chibambo, N.O.; Calabrese, M.A., Tuning the thermodynamic, optical, and rheological properties of thermoresponsive polymer solutions via silica nanoparticle shape and concentration. J. Colloid Interface Sci., 2022.
DOI: 10.1016/j.jcis.2022.08.139
Primary data available here

Magruder, B.R.; Park, S.J.; Collanton, R.P.; Bates, F.S.; Dorfman, K.D. Laves Phase Field in a Diblock Copolymer Alloy. Macromolecules, 2022, 55 (7), 2991-2998.
DOI: 10.1021/acs.macromol.2c00346
Primary data available here

Panwar, V.; Metaxas, A.E.; Dutcher, C.S. Polyelectrolyte solutions in Taylor-Couette flows. J Non-Newtonian Fluid Mechanics, 2021, 295, 104617.
DOI: 10.1016/j.jnnfm.2021.104617

Kumar, R.; Santa Chalarca, C.F.; Bockman, M.R.; Bruggen, C.V.; Grimme, C.J.; Dalal, R.J.; Hanson, M.G.; Hexum, J.K.; Reineke, T.M. Polymeric Delivery of Therapeutic Nucleic Acids. Chem. Rev., 2021, 121 (18), 11527-11652.
DOI: 10.1021/acs.chemrev.0c00997

Early, J.T.; Block, A.*; Yager, K.G.; Lodge, T.P. Molecular Weight Dependence of Block Copolymer Micelle Fragmentation Kinetics. J. Am. Chem. Soc., 2021, 143 (20), 7748–7758.
DOI: 10.1021/jacs.1c02147

Ohnsorg, M.L.; Prendergast, P.C.*; Robinson, L.L.; Bockman, M.R.; Bates, F.S.; Reineke, T.M. Bottlebrush Polymer Excipients Enhance Drug Solubility: Influence of End-Group Hydrophilicity and Thermoresponsiveness. ACS Macro Lett., 2021, 10 (3), 375–381.
DOI: 10.1021/acsmacrolett.0c00890

Chavez, R.O.; Lodge, T.P.; Alcoutlabi, M. Recent developments in centrifugally spun composite fibers and their performance as anode materials for lithium-ion and sodium-ion batteries. Materials Science and Engineering: B, 2021, 266, 115024.
DOI: 10.1016/j.mseb.2020.115024

Styles M.J.; Rodriguez, R.S.; Szlag, V.M.; Bryson, S.; Gao, Z.; Jung, S.; Reineke, T.M.; Haynes, C.L. Optimization of film over nanosphere substrate fabrication for SERS sensing of the allergen soybean agglutinin. Journal of Raman Spectroscopy, 2020, 52 (2).
DOI: 10.1002/jrs.6019

Narayan, S.; Metaxas, A.E.; Bachnak, R.; Neumiller, T.; Dutcher, C.S. Zooming in on the role of surfactants in droplet coalescence at the macroscale and microscale. Current Opinion in Colloid & Interface Science, 2020, 50, 101385.
DOI: 10.1016/j.cocis.2020.08.010

Kumar, R.; Le, N.; Tan, Z.; Brown, M.E.; Jiang, S.; Reineke, T.M. Efficient Polymer-Mediated Delivery of Gene-Editing Ribonucleoprotein Payloads through Combinatorial Design, Parallelized Experimentation, and Machine Learning. ACS Nano, 2020, 14 (12), 17626–17639.
DOI: 10.1021/acsnano.0c08549

Seed

Seed Publications resulting from primary MRSEC support

Druecke, B.; Mukherjee, R.; Cheng, X.; Lee, S. Collapse of a granular raft: Transition from single particle falling to collective creasing. Phys. Rev. Fluids, 2023, 8 (2), 024003.
DOI: 10.1103/physrevfluids.8.024003

Nair, S.; Noordhoek, K.; Lee, D.; Bartel, C.J.; Jalan, B. Solid-source metal-organic MBE for elemental Ir and Ru films. J. Vac. Sci. Technol. A, 2023, 41 (6) 062701.
DOI: 10.1116/6.0002955

He, J.; Spanolios, E,; Froehlich, C.E.; Wouters, C.L.; Haynes, C.L. Recent Advances in the Development and Characterization of Electrochemical and Electrical Biosensors for Small Molecule Neurotransmitters. ACS Sensors, 2023.
DOI: 10.1021/acssensors.3c00082

Froehlich, C.E.; He, J.; Haynes, C.L. Investigation of Charged Small Molecule–Aptamer Interactions with Surface Plasmon Resonance. Anal. Chem., 2023, 95, 2639-2644.
DOI: 10.1021/acs.analchem.2c04192

Kasturirangan, S.; Kamenev, A.; Burnell, F.J. Disordered graphene ribbons as topological multicritical systems. Phys. Rev. B, 2022, 106, 184206.
DOI: 10.1103/PhysRevB.106.184206

Kasturirangan, S.; Kamenev, A.; Burnell, F.J. Two parameter scaling in the crossover from symmetry class BDI to AI. Phys. Rev. B, 2022. 105, 174204.
DOI: 10.1103/PhysRevB.105.174204

Zhang, Y.; Choi, M.-K.; Haugstad, G.; Tadmor, E.B.; Flannigan, D.J. Holey Substrate-Directed Strain Patterning in Bilayer MoS₂. ACS Nano, 2021. 15, 20253-20260.
DOI: 10.1021/acsnano.1c08348
Primary data available here

Zhang, K.; Jiao, W.; Gonella, S. Tunable band gaps and symmetry breaking in magnetomechanical metastructures inspired by multilayer two-dimensional materials. Physical Review B, 2021, 104 (2), L020301.
DOI: 10.1103/PhysRevB.104.L020301

Hamill, A.; Heischmidt, B.; Sohn, E.; Shaffer, D.; Tsai, K.; Zhang, X.; Xi, X.; Suslov, A.; Berger, H.; Forró, L.; Burnell, F.J.; Shan, J.; Mak, K.F.; Fernandes, R.M.; Wang, K.; Pribiag, V.S. Two-fold symmetric superconductivity in few-layer NbSe₂. Nature Physics, 2021, 17, 949-954.
DOI: 10.1038/s41567-021-01219-x
Primary data available here

Seed Publications resulting from partial MRSEC support

Chi, Z.; Lee, S.; Yang, H.; Dolan, E.; Safeer, C.K.; Ingla-Aynés, J.; Herling, F.; Ontoso, N.; Martín-García, B.; Gobbi, M.; Low, T.; Hueso, L.E.; Casanova, F. Control of Charge-Spin Interconversion in van der Waals Heterostructures with Chiral Charge Density Waves. Adv. Mater., 2024.
DOI: 10.1002/adma.202310768

Ascencio, C.O.; Jiang, W.; de Sousa, D.J.P.; Lee, S.; Wang, J.-P.; Low, T. Enhanced spin Hall response from aligned Kramers-Weyl points in high Chern number semimetals. Phys. Rev. B, 2023, 108, L201404.
DOI: 10.1103/PhysRevB.108.L201404

Lee, I.-H.; Martin-Moreno, L.; Avouris, P.; Low, T.; Oh, S.-H. Switching the Symmetry of Graphene Plasmons with Nanoemitters for Ultimate Infrared-Light Confinement. Phys. Rev. Applied, 2023, 19, 064039.
DOI: 10.1103/PhysRevApplied.19.064039

Zhang, D.; Jiang, W.; Yun, H.; Benally, O.J.; Peterson, T.; Cresswell, Z.; Fan, Y.; Lv, Y.; Yu, G.; Garcia Barriocanal, J.; Swatek, P.W.; Mkhoyan, K.A.; Low, T.; Wang, J.-P. Robust negative longitudinal magnetoresistance and spin–orbit torque in sputtered Pt₃Sn and Pt₃Sn_xFe_1-x topological semimetal. Nature Comm., 2023, 14, 4151.
DOI: s41467-023-39408-2

Yun, H.; Zhang, D.; Birol, T.; Wang, J.-P.; Mkhoyan, A.K. Structural Anisotropy-Driven Atomic Mechanisms of Phase Transformations in the Pt-Sn System. Nano Lett., 2023, 23 (16), 7576-7583.
DOI: 10.1021/acs.nanolett.3c02162

Fan, Y.; Zhang, P.; Han, J.; Lv, Y.; Liu, L.; Wang, J.P. Observation of the Unidirectional Magnetoresistance in Antiferromagnetic Insulator Fe₂O₃/Pt Bilayers. Advanced Electronic Materials, 2023, 9 (8), 2300232.
DOI: 10.1002/aelm.202300232

Dasetty, S.; Zajac, J.W.; Sarupria, S. Exploitation of active site flexibility-low temperature activity relation for engineering broad range temperature active enzymes. Molecular Systems Design and Engineering, 2023.
DOI: 10.1039/d3me00013c

Willis, S.A.; Flannigan, D.J. Stable Photoemission from the Wehnelt Aperture Surface in 4D Ultrafast Electron Microscopy . Microsc. Microanal., 2023, 29 (1), 1842-1844.
DOI: 10.1093/micmic/ozad067.1103

Gruba, S.; Wu, X.; Spanolios, E.; He, J.; Xiong-Hang, K.; Haynes, C.L. Platelet Response to Allergens, CXCL10, and CXCL5 in the Context of Asthma. ACS Bio and Med Chem Au, 2023, 3 (1), 87-96.
DOI: 10.1021/acsbiomedchemau.2c00059

Yu, Z.; Frontiera, R.R. Ostensible Steady-State Molecular Cooling with Plasmonic Gold Nanoparticles ACS Nano, 2023, 17, 4306-4314
DOI: 10.1021/acsnano.2c08630

Yue, J.; Ayino, Y.; Truttman, T.K.; Gastiasoro, M.N.; Persky, E.; Khanukov, A.; Lee, D.; Thoutam, L.R.; Kalisky; Fernandes, R.M.; Pribiag, V.S.; Jalan, B. Anomalous transport in high-mobility superconducting SrTio₃ thin films. Sci. Adv., 2022, 8, 21.
DOI: 10.1126/sciadv.abl5668

Huang, D.; Lyu, D.; Wang, X.; Katz, M.B.; Zhang, D.; Wang, J.-P.; Gopman, D.B.; Wang, X. Temperature-dependent perpendicular anisotropy and Gilbert damping of L1₀ - FePd films: Role of noble-metal buffer layers. Phys. Rev. Mat., 2022, 6, 113402.
DOI: 10.1103/PhysRevMaterials.6.113402

Choi, M.k.; Pasetto, M.; Shen, Z.; Tadmor, E.B.; Kamensky, D. Atomistically-informed continuum modeling and isogeometric analysis of 2D materials over holey substrates. J Mech Phys Solids, 2023, 170, 105100.
DOI: 10.1016/j.jmps.2022.105100

Flannigan, D.J.; Curtis, W.A.; VandenBussche, E.J.; Zhang, Y. Low Repetition-Rate, High-Resolution Femtosecond Transmission Electron Microscopy. J. Mater. Chem. A, 2022.
DOI: 10.1063/5.0128109

Liu, J.; Anderson, R.; Schmalbach, K.M.; Sheridan, T.R.; Wang, Z.; Schweitzer, N.M.; Stein, A.; Mara, N.A.; Gomez-Gualdron, D.; Hupp, J.T. Insights into dual-functional modification for water stability enhancement of mesoporous zirconium metal–organic frameworks. J. Mater. Chem. A, 2022, 10, 17307.
DOI: 10.1039/d2ta03851j

Curtis, W.A.; Willis, S.; Flannigan, D. Single-Photoelectron Collection Efficiency in 4D Ultrafast Electron Microscopy. Phys. Chem. Chem. Phys., 2022.
DOI: 10.1039/D2CP01250B

Gruba, S.M.; Francis, D.H.; Meyer, A.F.; Spanolios, E.; He, J.; Meyer, B.M.; Kim, D.; Xiong-hang, K.; Haynes, C.L. Characterization of the Presence and Function of Platelet Opioid Receptors. ACS Meas. Sci. Au, 2022, 2 (1), 4-13.
DOI: 10.1021/acsmeasuresciau.1c00012

Gnabasik, R.A.; Suri, P.K.; Chen, J.; Flannigan, D.J. Imaging coherent phonons and precursor dynamics in LaFeAsO with 4D ultrafast electron microscopy. Phys. Rev. Mater., 2022.
DOI: 10.1103/PhysRevMaterials.6.024802

Yu, Z.; Frontiera, R.R. Intermolecular Forces Dictate Vibrational Energy Transfer in Plasmonic-Molecule Systems. ACS Nano, 2022.
DOI: 10.1021/acsnano.1c08431

Curtis, W.; Flannigan, D. J. Toward Å-fs-meV Resolution in Electron Microscopy: Systematic Simulation of the Temporal Spread of Single-Electron Packets. Phys. Chem. Chem. Phys., 2021, 23, 23544-23553.
DOI: 10.1039/D1CP03518E
Primary data available here

Zhang, Y.; Flannigan, D. J. Imaging Nanometer Phonon Softening at Crystal Surface Steps with 4D Ultrafast Electron Microscopy. Nano Lett., 2021, 21 (17), 7732-7338.
DOI: 10.1021/acs.nanolett.1c02524
Primary data available here

Reisbick, S.A.; Zhang, Y.; Chen, J.; Engen, P.E.; Flannigan, D.J. Coherent Phonon Disruption and Lock-In during a Photoinduced Charge-Density-Wave Phase Transition. J. Phys. Chem. Lett., 2021, 12 (27).
DOI: 10.1021/acs.jpclett.1c01673
Primary data available here

Sun, Y.; Kim, J.; Chatterjee, N.; Swisher, S.L. Investigation of the Determining Factors for the “Mobility Boost” in High‐k‐Gated Transparent Oxide Semiconductor Thin‐Film Transistors. Adv. Electron. Mater., 2021, 7.
DOI: 10.1002/aelm.202001037

Wang, Z.; Schmalbach, K.M.; Combs, R.L.; Chen, Y.; Penn, R.L.; Mara, N.A.; Stein, A. Effects of Phase Purity and Pore Reinforcement on Mechanical Behavior of NU-1000 and Silica-Infiltrated NU-1000 Metal–Organic Frameworks. ACS Appl. Mater. Interfaces, 2020, 12 (44), 49971–49981.
DOI: 10.1021/acsami.0c12877

Luo, R.; Chen, Y.; Lee, S. Particle-induced miscible fingering: Continuum limit. Phys. Rev. Fluids, 2020, 5, 094301.
DOI: 10.1103/PhysRevFluids.5.094301

Dai, C.; Lin, Z.; Agarwal, K.; Mikhael, C.; Aich, A.; Gupta, K.; Cho, J.H. Self-Assembled 3D Nanosplit Rings for Plasmon-Enhanced Optofluidic Sensing. Nano Lett., 2020, 20, 6697–6705.
DOI: 10.1021/acs.nanolett.0c02575

Publications resulting from use of Shared Facilities

Song, S.; Cui, S.; Sun, C.C.; Lodge, T.P.; Siegel, R.A. Crystallization Inhibition in Molecular Liquids by Polymers above the Overlap Concentration (c*): Delay of the First Nucleation Event. J. Pharm. Sci., 2024, 1-7.
DOI: 10.1016/j.xphs.2024.02.011

Keil, J.; Cote, B.M.; Chandrasekaran, A.L.; Ferry, V.E. Minimizing Roughness Induced Optical Losses for a Four-Terminal CdTe/Si Tandem Solar Cell. PRX Energy, 2023, 2, 023004.
DOI: 10.1103/PRXEnergy.2.023004

Donie, Y.J.; Ramamurthy, M.; Chakraborty, R.D.; Francis, L.F.; Frisbie, C.D.; Ferry, V.E. Roll-to-Roll Compatible Topochemical Wetting Control for Metamaterial Printing. Adv. Optical Mater., 2024.
DOI: 10.1002/adom.202302785

Wang, Y.; Frisbie, C.D. Four-Terminal Electrochemistry: A Back-Gate Controls the Electrochemical Potential of a 2D Working Electrode. J. Phys. Chem. C, 2024.
DOI: 10.1021/acs.jpcc.3c07198

Hsu, W.J.; Pettit, E.C.; Swartwout, R.; Kadosh, T.Z.; Srinivasan, S.; Wassweiler, E.L.; Haugstad, G.; Bulović, V.; Holmes, R.J. Efficient Metal-Halide Perovskite Photovoltaic Cells Deposited via Vapor Transport Deposition. Solar RRL, 2024, 8 (1), 2300758.
DOI: 10.1002/solr.202300758

Bista, B.; Golani, P.; Liu, F.; Truttmann, T.K.; Pavlidis, G.; Centrone, A.; Jalan, B.; Koester, S. Evaluating the thermal performance of perovskite SrSnO₃ field effect transistors. 2023, 2023-May.
DOI: 10.1109/itherm55368.2023.10177570

Xu, C.; Chaudhuri, S.; Held, J.; Andaraarachchi, H.P.; Schatz, G.C.; Kortshagen, U.R. Silver Nanoparticle Synthesis in Glycerol by Low-Pressure Plasma-Driven Electrolysis: The Roles of Free Electrons and Photons. Journal of Physical Chemistry Letters, 2023, 14 (44), 9960-9968.
DOI: 10.1021/acs.jpclett.3c02342

Hameed, S.; Wang, Z.; Gautreau, D.M.; Joe, J.; Olson, K.P.; Chi, S.; Gehring, P.M.; Hong, T.; Pajerowski, D.M.; Williams, T.J.; Xu, Z.; Matsuda, M.; Birol, T.; Fernandes, R.M.; Greven, M. Effect of random antiferromagnetic exchange on the spin waves in a three-dimensional Heisenberg ferromagnet. Physical Review B, 2023, 108 (13), 134406.
DOI: 10.1103/PhysRevB.108.134406

Kamdar, S.; Ghosh, D.; Lee, W.; Tatulea-Codrean, M.; Kim, Y.; Ghosh, S.; Kim, Y.; Cheepuru, T.; Lauga, E.; Lim, S.; Cheng, X. Multiflagellarity leads to the size-independent swimming speed of peritrichous bacteria. Proc. Nat. Acad. Sci., 2023, 120 (48), e2310952120.
DOI: 10.1073/pnas.2310952120

Chipangura, Y.E.; Spindler, B.D.; Bühlmann, P.; Stein, A. Design Criteria for Nanostructured Carbon Materials as Solid Contacts for Ion-Selective Sensors. Advanced Materials, 2023.
DOI: 10.1002/adma.202309778

Warkentin, C.L.; Frontiera, R.R. Quantifying the ultrafast and steady-state molecular reduction potential of a plasmonic photocatalyst. Proc. Nat. Acad. Sci., 2023, 120 (44) e2305932120.
DOI: 10.1073/pnas.2305932120

Campanaro, A.L.; Simcik, M.F.; Maurer-Jones, M.A.; Penn, R.L.Sewage sludge induces changes in the surface chemistry and crystallinity of polylactic acid and polyethylene films. Sci. Total Environ. 2023.
DOI: 10.1016/j.scitotenv.2023.164313

Chikhalikar, A.S.; Poerschke, D.L. Comparative Study of FeCrAlY and Sapphire Hot Corrosion by Mixed Oxide and Sulfate Deposits High Temp. Corrosion Mater. 2023, 100 321-344.
DOI: 10.1007/s11085-023-10182-2

Prebihalo, E.A.; Luke, A.M.; Reddi, Y.; LaSalle, C.J.; Shah, V.M.; Cramer, C.J.; Reineke, T.M. Radical ring-opening polymerization of sustainably-derived thionoisochromanone. Chemical Science, 2023, 14 (21), 5689-5698.
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Hameed, S.; El-Khatib, S.; Olson, K.P.; Yu, B.; Williams, T.J.; Hong, T.; Sheng, Q.; Yamakawa, K.; Zang, J.; Uemura, Y.J.; Zhao, G.Q.; Jin, C.Q.; Fu, L.; Gu, Y.; Ning, F.; Cai, Y.; Kojima, K.M.; Freeland, J.W.; Matsuda, M.; Leighton, C.; Greven, M. Nature of the ferromagnetic-antiferromagnetic transition in Y1-xLaxTi O3. Physical Review B, 2021, 104 (2), 024410.
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Chawla, A; Bates, F.S.; Dorfman, K.D.; Morse, D.C. Identifying a critical micelle temperature in simulations of disordered asymmetric diblock copolymer melts. Phys. Rev. Mater, 2021, 5, L092601.
DOI: 10.1103/PhysRevMaterials.5.L092601
Primary data available here

Hameed, S.; Joe, J.; Gautreau, D.M.; Freeland, J.W.; Birol, T.; Greven, M. Two-component electronic phase separation in the doped Mott insulator Y_1−xCa_xTiO₃. Physical Review B, 2021, 104, 045112.
DOI: 10.1103/PhysRevB.104.045112

Nunn, W.; Sandlass, S.; Wegner, M.; Haislmaier, R.; Kumar, A.; Tangi, M.; LeBeau, J.; Quandt, E.; James, R.D.; Jalan, B. Hybrid molecular beam epitaxy growth of BaTiO₃ films. Journal of Vacuum Science & Technology A, 2021, 39, 040404.
DOI: 10.1116/6.0001140

Beaudette, C.A.; Andaraarachchi, H.P.; Wu, C-C.; Kortshagen, U.R. Inductively coupled nonthermal plasma synthesis of aluminum nanoparticles. Nanotechnology, 2021, 32 (39), 395601.
DOI: 10.1088/1361-6528/ac0cb3

Cote, B.M.; Slauch, I.M.; Deceglie, M.G.; Silverman, T.J.; Ferry, V.E. Light Management in Bifacial Photovoltaics with Spectrally Selective Mirrors. CS Appl. Energy Mater., 2021, 4 (6), 5397–5402.
DOI: 10.1021/acsaem.1c01236

Ishibashi, J.S.A.; Pierce, I.C.; Chang, A.B.; Zografos, A.; El-Zaatari, B.M.; Fang, Y.; Weigand, S.J.; Bates, F.S.; Kalow, J.A. Mechanical and Structural Consequences of Associative Dynamic Cross-Linking in Acrylic Diblock Copolymers. Macromolecules, 2021, 54 (9), 3972–3986.
DOI: 10.1021/acs.macromol.0c02744

Ayala, J.; Ramirez, D.; Myers, J.C.; Lodge, T.P.; Parsons, J.; Alcoutlabi, M. Performance and morphology of centrifugally spun Co₃O₄/C composite fibers for anode materials in lithium-ion batteries. Journal of Materials Science, 2021, 56, 16010–16027.
DOI: 10.1007/s10853-021-06285-3

Lau, C.M.; Kim, S.S.; Lillie, L.M.; Tolman, W.B.; Reineke, T.M.; Ellison, C.J. Structural Basis for the Different Mechanical Behaviors of Two Chemically Analogous, Carbohydrate-Derived Thermosets. ACS Macro Lett., 2021, 10 (5), 609–615.
DOI: 10.1021/acsmacrolett.1c00041

Schmalbach, K.M.; Lin, A.C.; Bufford, D.C.; Wang, C.; Sun, C.C.; Mara, N.A. Nanomechanical mapping and strain rate sensitivity of microcrystalline cellulose. Journal of Materials Research, 2021, 36, 2251–2265.
DOI: 10.1557/s43578-021-00138-0

Slauch, I.M.; Deceglie, M.G.; Silverman, T.J.; Ferry, V.E. Optical approaches for passive thermal management in c-Si photovoltaic modules. Cell Reports Physical Science, 2021, 2 (5), 100430.
DOI: 10.1016/j.xcrp.2021.100430
Primary data available here

Namgung, S.; Koester, S.J.; Oh, S-H. Ultraflat Sub-10 Nanometer Gap Electrodes for Two-Dimensional Optoelectronic Devices. ACS Nano, 2021, 15 (3), 5276–5283.
DOI: 10.1021/acsnano.0c10759

Mueller, A.J.; Lindsay, A.P.; Jayaraman, A.; Lodge, T.P.; Mahanthappa, M.K.; Bates, F.S. Quasicrystals and Their Approximants in a Crystalline–Amorphous Diblock Copolymer. Macromolecules, 2021, 54 (6), 2647–2660.
DOI: 10.1021/acs.macromol.0c02871

Kang, H.; Elmer, W.; Shen, Y.; Zuverza-Mena, N.; Ma, C.; Botella, P.; White, J.C.; Haynes, C.L. Silica Nanoparticle Dissolution Rate Controls the Suppression of Fusarium Wilt of Watermelon (Citrullus lanatus). Environ. Sci. Technol., 2021, 55, 13513-13522.
DOI: 10.1021/acs.est.0c07126

Truttmann, T.K.; Liu, F.; Garcia-Barriocanal, J.; James, R.D.; Jalan, B. Strain Relaxation via Phase Transformation in High-Mobility SrSnO₃ Films. ACS Appl. Electron. Mater., 2021, 3 (3), 1127–1132.
DOI: 10.1021/acsaelm.0c00997

Nguyen, Q.V.; Xie, Z.; Frisbie, C.D. Quantifying Molecular Structure-Tunneling Conductance Relationships: Oligophenylene Dimethanethiol vs Oligophenylene Dithiol Molecular Junctions. J. Phys. Chem. C, 2021, 125 (7), 4292–4298.
DOI: 10.1021/acs.jpcc.0c11514

Cai, X.; Yue, J.; Xu, P.; Jalan, B.; Pribiag, V.S. From weak antilocalization to Kondo scattering in a magnetic complex oxide interface. Phys. Rev. B, 2021, 103, 115434.
DOI: 10.1103/PhysRevB.103.115434

Nguyen, Q.V.; Frisbie, C.D. Hopping Conductance in Molecular Wires Exhibits a Large Heavy-Atom Kinetic Isotope Effect. J. Am. Chem. Soc., 2021, 143 (7), 2638–2643.
DOI: 10.1021/jacs.0c12244

Zhang, B.; Xie, S.; Lodge, T.P.; Bates, F.S. Phase Behavior of Diblock Copolymer–Homopolymer Ternary Blends with a Compositionally Asymmetric Diblock Copolymer. Macromolecules, 2021, 54 (1), 460–472.
DOI: 10.1021/acs.macromol.0c01745

Valentine, C.S.; Jayaraman, A.; Mahanthappa, M.K.; Walker, L.M. Shear-Modulated Rates of Phase Transitions in Sphere-Forming Diblock Oligomer Lyotropic Liquid Crystals. ACS Macro Lett., 2021, 10, 538–544.
DOI: 10.1021/acsmacrolett.1c00154

McCutcheon, C.J.; Zhao, B.; Jin, K.; Bates, F.S.; Ellison, C.J. Crazing Mechanism and Physical Aging of Poly(lactide) Toughened with Poly(ethylene oxide)-block-poly(butylene oxide) Diblock Copolymers. Macromolecules, 2020, 53 (22), 10163–10178.
DOI: 10.1021/acs.macromol.0c01759

VandenBussche, E.J.; Flannigan, D.J. High-resolution analogue of time-domain phonon spectroscopy in the transmission electron microscope. Phil. Trans. R. Soc. A., 2020, 378, 20190598.
DOI: 10.1098/rsta.2019.0598
Primary data available here

Van Bruggen, C.; Punihaole, D.; Keith, A.R.; Schmitz, A.J.; Tolar, J.; Frontiera, R.R.; Reineke, T.M. Quinine copolymer reporters promote efficient intracellular DNA delivery and illuminate a protein-induced unpackaging mechanism. Proc. Nat. Acad. Sci., 2020, 117 (52), 32919-32928.
DOI: 10.1073/pnas.2016860117

Su, Q.; Zhen, X.V.; Nelson, J.T.; Li, R.; Bühlmann, P.; Sherwood, G.; Koester, S.J. Ultraclean Graphene Transfer Using a Sacrificial Fluoropolymer Nanolayer: Implications for Sensor and Electronic Applications. ACS Appl. Nano Mater., 2020, 3 (12), 11998–12007.
DOI: 10.1021/acsanm.0c02482

VandenBussche, E.J.; Clark, C.P.; Holmes, R.J.; Flannigan, D.J. Mitigating Damage to Hybrid Perovskites Using Pulsed-Beam TEM. ACS Omega, 2020, 5 (49), 31867-31871.
DOI: 10.1021/acsomega.0c04711
Primary data available here

Prakash, A.; Wang, T.; Choudhary, R.; Haugstad, G. D.; Gladfelter, W.L.; Jalan, B. Precursor selection in hybrid molecular beam epitaxy of alkaline-earth stannates. Journal of Vacuum Science & Technology A, 2020, 38, 063410.
DOI: 10.1116/6.0000590

Publications resulting from the Materials Research Facilities Network (MRFN) support or other users of Shared Facilities

Lin, Y.-H.; Bohn, A.; Cheng, J.Y.; von der Handt, A.; Mara, N.A.; Poerschke, D.L. Gas nitriding behavior of refractory metals and implications for multi-principal element alloy design. J. Alloys and Compounds, 2023, 947, 169568.
DOI: 10.1016/j.jallcom.2023.169568, MRFN

Su, D.; Wu, K.; Srinivasan, K.; Nemati Porshokouh, Z.; Zamani, R.; Chugh, V.K.; Saha, R.; Franklin, R.; Modiano, J.; Stadler, B. et al. Ultra-Flexible Giant Magnetoresistance Biosensors for Lab-on-a-Needle Biosensing. Adv. Mater. Interfaces, 2023, 10, 2201417.
DOI: 10.1002/admi.202201417, MRFN

Su, D.; Um, J.; Moreno, J.; Nemati, Z.; Srinivasan, K.; Chen, J.; Zamani Kouhpanji, M.R.; Shore, D.; Wu, K.; Kosel, J.; Modiano, J.F.; Franklin, R.; Wang, J.-P.; Stadler, B. GMR biosensing with magnetic nanowires as labels for the detection of osteosarcoma cells. Sensors and Actuators A: Phys., 2023, 350, 114115.
DOI: 10.1016/j.sna.2022.114115, MRFN

Qiao, Y.; Ma, Z.; Onyango, C.; Cheng, X.; Dorfman, K.D. DNA fragmentation in a steady shear flow. Biomicrofluidics, 2022, 16 (5), 054109.
DOI: 10.1063/5.0109361, MRFN

Song, S.; Siegel, R.A.; Sanchez Uribe, M.A.; Calderer, M.C.; Henao, D. Experiments, Modelling, and Simulations for a Gel Bonded to a Rigid Substrate. J. Elasticity, 2022.
DOI: 10.1007/s10659-022-09911-6

Bhattarai, S.; Temme, H.R.; Jain, A.; Badalamenti, J.P.; Gralnick, J.A.; Novak, P.J. The potential for bacteria from carbon-limited deep terrestrial environments to participate in chlorine cycling. Microbiology Ecology, 2022.
DOI: 10.1093/femsec/fiac054

Hamadani, C.M.; Chandrasiri, I.; Yaddehige, M.L.; Dasanayake, G.S.; Owolabi, I.; Flynt, A.; Hossain, M.; Liberman, L.; Lodge, T.P.; Werfel, T.A.; Watkins, D.L.; Tanner, E.E.L. Improved nanoformulation and bio-functionalization of linear-dendritic block copolymers with biocompatible ionic liquids. Nanoscale, 2022.
DOI: 10.1039/D2NR00538G, MRFN

Godbole, E.; von der Handt, A.; Poerschke, D. Apatite and garnet stability in the Al–Ca–Mg–Si–(Gd/Y/Yb)–O systems and implications for T/EBC: CMAS reactions. J. Am. Ceram. Soc., 2021.
DOI: 10.1111/jace.18179, MRFN

Sonje, J.; Thakral, S.; Krueger, S.; Suryanarayanan, R. Reversible Self-Association in Lactate Dehydrogenase during Freeze–Thaw in Buffered Solutions Using Neutron Scattering. Mol. Pharmaceutics, 2021.
DOI: 10.1021/acs.molpharmaceut.1c00666

Siehr, A.; Flory, C.; Callaway, T.; Schumacher, R.J.; Siegel, R.A.; Shen, W. Implantable and Degradable Thermoplastic Elastomer. ACS Biomater. Sci. Eng., 2021.
DOI: 10.1021/acsbiomaterials.1c01123

Fischer, N.G. Chen, X.; Astleford-Hopper, K.; He, J.; Mullikin, A.F.; Mansky, K.C.; Aparicio, C. Antimicrobial and enzyme-responsive multi-peptide surfaces for bone-anchored devices. Materials Science and Engineering: C, 2021, 125, 112108.
DOI: 10.1016/j.msec.2021.112108

Thakral, S.; Kim, K. Small-angle scattering for characterization of pharmaceutical materials. TrAC Trends in Analytical Chemistry, 2021, 134, 116144.
DOI: 10.1016/j.trac.2020.116144

Altay, E.; Jang, Y.J.; Kua, X.Q.; Hillmyer, M.A. Synthesis, Microstructure, and Properties of High-Molar-Mass Polyglycolide Copolymers with Isolated Methyl Defects. Biomacromolecules, 2021, 22 (6), 2532–2543.
DOI: 10.1021/acs.biomac.1c00269

UMN Partnership for Research and Education in Materials Science (PREM): University of Texas Rio Grande Valley (UTRGV) Award DMR-2122178 & 1523577. Participant Co-authors denoted with an *

Santa Chalarca, C.F.; Dalal, R.J.; Chapa, A.*; Hanson, M.G.; Reineke, T.M. Cation Bulk and pK_a Modulate Diblock Polymer Micelle Binding to pDNA. ACS Macro Lett., 2022. 11, 4, 588-594.
DOI: 1010.21/acsmacrolett.2c00015

Schmidt, J.; Usgaonkar, S.S.; Kumar, S.; Lozano, K.; Ellison, C.J., Advances in Melt Blowing Process Simulations. Ind. Eng. Chem. Res., 2022, 61, 65-85.
DOI: 10.1021/acs.iecr.1c03444

Izquierdo, N.; Myers, J.C.; Golani, P.; De Los Santos, A.*; Seaton, N.; Koester, S.J.;Campbell, S.A. Growth of black arsenic phosphorus thin films and its application for field-effect transistors. Nanotechnology, 2021, 32 (32), 325601.
DOI: 10.1088/1361-6528/abfc09

De Leo, C.T.; Dannangoda, G.C.; Hobosyan, M.A.; Held, J.T.; Samghabadi, F.S.; Khodadadi, M.; Litvinov, D.; Mkhoyan, K.A.; Martirosyan, K.S. Carbon combustion synthesis of Janus-like particles of magnetoelectric cobalt ferrite and barium titanate. Ceramics International, 2021, 47 (4), 5415-5422.
DOI: 10.1016/j.ceramint.2020.10.123

Lopez,D.; Chowdhury, A.R.; Abdullah, A.M.;Karim Sadaf, M.-UI.;Martinez, I.;Choudhury, B.D.; Danti, S.; Ellison, C.J.; Lozano, K.; Uddin, M.J. Polymer Based Triboelectric Nanogenerator for Cost-Effective Green Energy Generation and Implementation of Surface-Charge Engineering. Energy Tech., 2021.
DOI: 10.1002/ente.202001088

Lopez, J.; Gonzalez, R.; Ayala, J.; Cantu, J.; Castillo, A.; Parsons, J.; Myers, J.; Lodge, T.P.; Alcoutlabi, M. Centrifugally spun TiO₂/C composite fibers prepared from TiS₂/PAN precursor fibers as binder-free anodes for LIBS. Journal of Physics and Chemistry of Solids, 2021, 149, 109795.
DOI: 10.1016/j.jpcs.2020.109795

Chavez, R.O.; Lodge, T.P.; Huitron, J.; Chipara, M.; Alcoutlabi, M. Centrifugally spun carbon fibers prepared from aqueous poly(vinylpyrrolidone) solutions as binder‐free anodes in lithium‐ion batteries. Journal of Applied Polymer Science, 2020.
DOI: 10.1002/app.50396

Villarreal, J.; Chavez, R.O.; Chopade, S.A.; Lodge, T.P.; Alcoutlabi, M. The use of succinonitrile as an electrolyte additive for composite-fiber membranes in lithium-ion batteries. Membranes, 2020, 10 (3) 45.
DOI: 10.3390/membranes10030045

Zuniga, L.; Gonzalez, G.; Orrostieta Chavez, R.; Myers, J.C.; Lodge, T.P.; Alcoutlabi, M. Centrifugally Spun α-Fe₂O₃/TiO₂/Carbon Composite Fibers as Anode Materials for Lithium-Ion Batteries. Appl. Sci. 2019, 9, 4032.
DOI: 10.3390/app9194032

Akia, M.; Mkhoyan, A.; Lozano, K. Synthesis of multiwall α-Fe₂O₃ hollow fibers via a centrifugal spinning technique. Materials Science and Engineering C, 2019, 102, 552-557.
DOI: 10.1016/j.msec.2019.04.085

Boyle, W.S.; Chen, W.; Rodriguez, A.; Linn, S.; Tolar, J.; Lozano, K.; Reineke, T.M. Ternary Composite Nanofibers Containing Chondroitin Sulfate Scavenge Inflammatory Chemokines from Solution and Prohibit Squamous Cell Carcinoma Migration. ACS Applied Bio Materials, 2019, 2 (2), 619-624.
DOI: 10.1021/acsabm.8b00690

Akia, M.; Cremar, L.; Chipara, M.; Edgar Muñoz, E.; Cortez, H.; de Santiago, H.; Rodríguez-Macías, F.J.; Vega-Cantú, Y.I.; Arandiyan, H.; Sun, H.; Lodge, T.P.; Mao, Y.; Lozano, K. In Situ Production of Graphene−Fiber Hybrid Structures. Appl. Mater. Interfaces, 2017, 9, 25474-25480.
DOI: 10.1021/acsami.7b07509

Research Experiences for Undergraduates (REU) and Research Experiences for Teachers (RET): 2014 - Present. Participant Co-authors denoted with an *

Buenaflor, J.P.; Lydon, C.K.*; Zimmerman, A.; Desutter, O.L.*; Wissinger, J.E. Student explorations of calcium alginate bead formation by varying pH and concentration of acidic beverage juices. J. Chem. Teacher Intl., 2022.
DOI: 10.1515/cti-2021-0027

Santa Chalarca, C.F.; Dalal, R.J.; Chapa, A.*; Hanson, M.G.; Reineke, T.M. Cation Bulk and pK_a Modulate Diblock Polymer Micelle Binding to pDNA. ACS Macro Lett., 2022. 11, 4, 588-594.
DOI: 1010.21/acsmacrolett.2c00015

Corcoran, E.R.; Lydon, C.*; Enright, M.C.; Buenaflor, J.P.; Anderson, K.; Wissinger, J.E. Thirst for a Solution: Alginate Biopolymer Experiments for the Middle and High School Classroom. J. Chem. Educ., 2021, 99 (2), 1021-1025.
DOI: 10.1021/acs.jchemed.1c00905

Lee, H.R.; Kim, D.W.; Jones, V.O.*; Choi, Y.; Ferry, V.E.; Geller, M.A.; Azarin, S.M. Sonosensitizer-Functionalized Graphene Nanoribbons for Adhesion Blocking and Sonodynamic Ablation of Ovarian Cancer Spheroids. Adv. Healthcare Mat., 2021, 10 (13), 2001368.
DOI: 10.1002/adhm.202001368

Early, J.T.; Block, A.*; Yager, K.G.; Lodge, T.P. Molecular Weight Dependence of Block Copolymer Micelle Fragmentation Kinetics. J. Am. Chem. Soc., 2021, 143 (20), 7748–7758.
DOI: 10.1021/jacs.1c02147

Izquierdo, N.; Myers, J.C.; Golani, P.; De Los Santos, A.*; Seaton, N.; Koester, S.J.; Campbell, S.A. Growth of black arsenic phosphorus thin films and its application for field-effect transistors. Nanotechnology, 2021, 32 (32), 325601.
DOI: 10.1088/1361-6528/abfc09

Wissinger, J.E.; Knutson, C.M.*; Javner, C.H.* Designing Impactful Green and Sustainable Chemistry Workshops for High School Teachers. 2020, 1344, 1-14.
DOI: 10.1021/bk-2020-1344.ch001

Lam, T.; Moy, A.*; Lee, H.R.; Shao, Q.; Bischof, J.C.; Azarin, S.M. Iron oxide‐loaded polymer scaffolds for non‐invasive hyperthermic treatment of infiltrated cells. AIChe Journal, 2020, 66 (12), e17001.
DOI: 10.1002/aic.17001

Beaudette, C.A.; Held, J.T.; Greenberg, B.L.; Nguyen, P.H.*; Concannon, N.M.; Holmes, R.J.; Mkhoyan, K.A.; Aydil, E.S.; Kortshagen, U.R. Plasmonic nanocomposites of zinc oxide and titanium nitride. Journal of Vacuum Science & Technology A, 2020, 38, 042404.
DOI: 10.1116/1.5142858

Karavolias, M.G.; Elder, J.B.; Ness, E.M.*; Mahanthappa, M.K. Order-to-Disorder Transitions in Lamellar Melt Self-Assembled Core-Shell Bottlebrush Polymers. ACS Macro Letters, 2019, 8 (12), 1617-1622.
DOI: 10.1021/acsmacrolett.9b00782

Jayaraman, A.; Zhang, D.Y.*; Dewing, B.L.; Mahanthappa, M.K. Path-Dependent Preparation of Complex Micelle Packings of a Hydrated Diblock Oligomer. ACS Central Science, 2019, 5 (4), 619-628.
DOI: 10.1021/acscentsci.8b00903

Dwyer, J.D.; Diaz, E.J.*; Webber, T.E.; Katzenberg, A.; Modestino, M.A.; Aydil, E.S. Quantum confinement in few layer SnS nanosheets. Nanotechnology, 2019, 30 (24), 245705.
DOI: 10.1088/1361-6528/ab0e3e

Kumar, G.; Bossert, H.*; Dauenhauer, P.J.; Tsapatsis, M. Catalysis-in-a-Box: A Micro-flow Catalytic Reactor Integrated within a Gas Chromatograph for Automated Kinetic Measurements. Catalysis, 2019.
DOI: 10.26434/chemrxiv.11288885.v2

Knutson, C.M.*; Hilker, A.P.; Tolstyka, Z.P.; Anderson, C.B.; Wilbon, P.A.; Mathers, R.T.; Wentzel, M.T.; Perkins, A.L.; Wissinger, J.E. Dyeing to Degrade: A Bioplastics Experiment for College and High School Classrooms. Advanced Healthcare Materials, 2019, 96 (11), 2565-2573.
DOI: 10.1021/acs.jchemed.9b00461

Pham, P.T.T.; Young, V.G.; Bader, M.M.* The impact of vinylene bridges and side chain alkyl groups on the solid state structures of tricyanovinyl-substituted thiophenes. CrystEngComm, 2018, 20 (1), 128-132.
DOI: 10.1039/c7ce01574g

Wilkinson, N.; Metaxas, A.; Quinney, C.*; Wickramaratne, S.; Reineke, T.M.; Dutcher, C.S. pH dependence of bentonite aggregate size and morphology on polymer-clay flocculation. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2018, 537, 281-286.
DOI: 10.1016/j.colsurfa.2017.10.007

Finkenstaedt-Quinn, S.A.; Hudson-Smith, N.V.; Styles, M.J.; Maudal, M.K.*; Juelfs, A.R.; Haynes, C.L. Expanding the Educational Toolset for Chemistry Outreach: Providing a Chemical View of Climate Change through Hands-On Activities and Demonstrations Supplemented with TED-Ed Videos. Journal of Chemical Education, 2018, 95 (6), 985-990.
DOI: 10.1021/acs.jchemed.7b00948

Larsen, M.B.; Herzog, S.E.*; Quilter, H.C.; Hillmyer, M.A. Activated Polyacrylamides as Versatile Substrates for Postpolymerization Modification. ACS Macro Letters, 2018, 7 (1), 122-126.
DOI: 10.1021/acsmacrolett.7b00896

Chopade, S.A.; Au, J.G.*; Li, Z.; Schmidt, P.W.; Hillmyer, M.A.; Lodge, T.P. Robust Polymer Electrolyte Membranes with High Ambient-Temperature Lithium-Ion Conductivity via Polymerization-Induced Microphase Separation. ACS Applied Materials and Interfaces, 2017, 9 (17), 14561-14565.
DOI: 10.1021/acsami.7b02514

Knutson, C.M.*; Schneiderman, D.K.; Yu, M.; Javner, C.H.*; Distefano, M.D.; Wissinger, J.E. Polymeric Medical Sutures: An Exploration of Polymers and Green Chemistry. Journal of Chemical Education, 2017, 94 (11), 1761-1765.
DOI: 10.1021/acs.jchemed.6b00835

Johnson, S.M.; Javner, C.*; Hackel, B.J. Development and Implementation of a Protein-Protein Binding Experiment to Teach Intermolecular Interactions in High School or Undergraduate Classrooms. Journal of Chemical Education, 2017, 94 (3), 367-374.
DOI: 10.1021/acs.jchemed.6b00323

Hall, C.C.; Zhou, C.; Danielsen, S.P.O.*; Lodge, T.P. Formation of Multicompartment Ion Gels by Stepwise Self-Assembly of a Thermoresponsive ABC Triblock Terpolymer in an Ionic Liquid. Macromolecules, 2016, 49 (6), 2298-2306.
DOI: 10.1021/acs.macromol.5b02789

Krumm, C.; Maduskar, S.; Paulsen, A.D.; Anderson, A.D.; Barberio, N.L.*; Damen, J.N.; Beach, C.A.; Kumar, S.; Dauenhauer, P.J. Micro-ratcheted surfaces for a heat engine biomass conveyor. Energy and Environmental Science, 2016, 9 (5), 1645-1649.
DOI: 10.1039/c6ee00519e

Campos, A.R.; Knutson, C.M.*; Knutson, T.R.; Mozzetti, A.R.; Haynes, C.L.; Penn, R.L. Quantifying Gold Nanoparticle Concentration in a Dietary Supplement Using Smartphone Colorimetry and Google Applications. Journal of Chemical Education, 2016, 93 (2), 318-321.
DOI: 10.1021/acs.jchemed.5b00385

Agrawal, K.V.; Topuz, B.; Pham, T.C.T.; Nguyen, T.H.; Sauer, N.*; Rangnekar, N.; Zhang, H.; Narasimharao, K.; Basahel, S.N.; Francis, L.F.; Macosko, C.W.; Al-Thabaiti, S.; Tsapatsis, M.; Yoon, K.B. Oriented MFI membranes by gel-less secondary growth of sub-100 nm MFI-nanosheet seed layers. Advanced Materials, 2015, 27 (21), 3243-3249.
DOI: 10.1002/adma.201405893

Knutson, T.R.; Knutson, C.M.*; Mozzetti, A.R.; Campos, A.R.; Haynes, C.L.; Penn, L.R. A Fresh Look at the Crystal Violet Lab with Handheld Camera Colorimetry. J. Chem. Ed., 2015.
DOI: 10.1021/ed500876y

Mousavi, M.P.S.; Gunsolus, I.L.; Pérez De Jesús, C.E.*; Lancaster, M.; Hussein, K.; Haynes, C.L.; Bühlmann, P. Dynamic silver speciation as studied with fluorous-phase ion-selective electrodes: Effect of natural organic matter on the toxicity and speciation of silver. Science of the Total Environment, 2015, 537, 453-461.
DOI: 10.1016/j.scitotenv.2015.07.151

Gunawan, A.A.; Chernomordik, B.D.; Plemmons, D.S.*; Deng, D.D.; Aydil, E.S.; Mkhoyan, K.A. Plasmonic interactions through chemical bonds of surface ligands on PbSe nanocrystals. Chemistry of Materials, 2014, 26 (10), 3328-3333.
DOI: 10.1021/cm501254m

Price, K.; Wu, W.; Wood, K.; Kong, S.*; McCormick, A.; Francis, L. Stress development and film formation in multiphase composite latexes. Journal of Coatings Technology and Research, 2014, 11 (6), 827-839.
DOI: 10.1007/s11998-014-9606-7

Meyer, A.F.; Knutson, C.M.*; Finkenstaedt-Quinn, S.A.; Gruba, S.M.; Meyer, B.M.; Thomspon, J.W.; Mauerer-Jones, M.A.; Halderman, S.; Tillman, A.S.; DeStefano, L.; Haynes, C.L. Activities for Middle School Students To Sleuth a Chemistry “Whodunit” and Investigate the Scientific Method. J. Chem. Ed., 2014.
DOI: 10.1021/ed4006562

Anglin, T.C.; Lane, A.P.*; Massari, A.M. Real-time structural evolution at the interface of an organic transistor during thermal annealing. Journal of Materials Chemistry C, 2014, 2 (17), 3390-3400.
DOI: 10.1039/c3tc32063d

Paulsen, B.D.; Speros, J.C.; Claflin, M.S.*; Hillmyer, M.A.; Frisbie, C.D. Tuning of HOMO energy levels and open circuit voltages in solar cells based on statistical copolymers prepared by ADMET polymerization. Polymer Chemistry, 2014, 5 (21), 6287-6294.
DOI: 10.1039/c4py00832d

Archived Publications

For older publications, see the annual reports (pdf format) below:

MRSEC Award DMR-2011401 (September 1, 2020 – August 31, 2026)

MRSEC Award DMR-1420013 (November 1, 2014 – September 30, 2021)

MRSEC Award DMR-0819885 (September 1, 2008 – August 31, 2014)

MRSEC Award DMR-0212302 (September 1, 2002 – August 31, 2008)

MRSEC Award DMR-9809364 (September 1, 1998 – August 31, 2002)

Funded by the National Science Foundation through the University of Minnesota MRSEC under Award Number DMR-2011401

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publications